Facebook Pixel Chemistry - Emeritus Faculty | Western Kentucky University Skip to main content
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    [First_Name] => Norman
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    [Title] => Professor Emeritus
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    [First_Name] => Wei-Ping
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    [Title] => Assistant to the President & Sumpter Emeritus Professor of Chemistry
    [Office] => Institute for Combustion Science and Environmental Technology
    [Phone] => 270-745-2272
    [Website] => http://www.wku.edu/ci
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    [Section_Value2] => <p>Coal combustion, emission control, nanocomposite, thermal characterization of polymers and materials &nbsp;</p>
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    [Section_Value3] => <p>Dr. Wei-Ping Pan, Assistant to the President, and Director of Combustion Science and Environmental Technology at Western Kentucky University, received his B.S. degree in Chemical Engineering from Chung Yuan University, Taiwan and his Ph.D. in Physical Chemistry from Michigan Technological University in1986. Dr. Pan has taught at Western Kentucky University since 1986. Dr. Pan was named the Sumpter Professor of Chemistry at Western in 1993 and was named a Fellow of the North American Thermal Analysis Society (NATAS) in 1997. He served as President of NATAS in 2001. He also received the Distinguished Service Award from NATAS in 2004. Dr. Pan has been selected as the 2008 recipient of the Mettler Award. The award is the NATAS&rsquo; highest honor and recognizes distinguished achievement in the field of thermal analysis. Dr. Pan has published more than 140 peer-reviewed papers in the last 20 years, the majority of which are related to coal combustion and emissions, and materials characterization. He has pioneered work in the area of clean coal technology, emission control, and thermal analysis involving effluent gas analysis and has used the TG/FTIR/MS technique extensively in the study of many different types of materials. Dr. Pan has been selected to receive the 2006 Distinguished College/University Scientist Superlative Award of the Kentucky Academy of Science. Dr. Pan has been the project director of more than 70 projects supported (more than $17,000,000 was awarded) by external agencies, including NSF, the US DOD, the US DOE, NASA, US EPA, EPRI, Illinois Clean Coal Institute, and several private industries. He also services as President of the Overseas Chinese Environmental Engineers and Scientists Association in 2010. Dr. Pan also has been appointed as a visiting professor for Zhijiang University, Shanghai Jiao Tong University, Harbin Institute of Technology, Southeast University, Huazhong University of Science and Technology, North China Electric Power University, Taiyuan University of Science and Technology, Hefei University of Technology, China Ming University, University of Shanghai for Science and Technology and Anhui University of Science and Technology.</p>
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    [Title] => Emeritus Professor, Director, Kentucky Science Olympiad
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    [Section_Value1] => <p>CHEM 111&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; Intro to Forensic Chemistry</p>
<p>CHEM 430&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; Forensic Chemistry</p>
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    [Last_Name] => Slocum
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    [Title] => Emeritus Research Professor
    [Office] => TCCW 437
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<p style="text-align: justify;"><strong><span style="font-family: Calibri; font-size: medium;">organic, organometallic chemistry</span></strong></p>
<p style="text-align: justify;"><span style="font-family: Calibri; font-size: medium;">aromatic substitution, organolithiums, metalations</span></p>
<p style="text-align: justify;"><span style="font-family: Calibri;"><span style="font-size: medium;">The potential of our research lies in the discovery and catalysis of C-H and C-Br activation of aromatic systems. This in turn leads to regiospecific ortho- and para-derivative formation, an impossible task under normal electrophilic substitution conditions. Primary emphasis is on the utility afforded by <em>ortho</em></span><span style="font-size: medium;">-lithiations which lead to formation of numerous </span><em><span style="font-size: medium;">ortho</span></em><span style="font-size: medium;">-aryllithium intermediates. Our novel approach to this undertaking features use of </span><em><span style="font-size: medium;">n</span></em><span style="font-size: medium;">-BuLi in promoted hydrocarbon media. Promoted hydrocarbon media also facilitates the halogen/metal exchange at ambient temperature. This approach provides a number of advantages over the extant textbook as well as industrial practices:</span></span></p>
</div>
<p style="text-align: justify;">&nbsp;</p>
<div style="text-align: justify;">
<ul>
<li><span style="font-size: medium;">&middot;</span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <span style="font-family: Calibri; font-size: medium;">Regiospecificity</span></li>
<li><span style="font-size: medium;">&middot;</span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <span style="font-family: Calibri; font-size: medium;">Efficiency</span></li>
<li><span style="font-size: medium;">&middot;</span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <span style="font-family: Calibri; font-size: medium;">Sustainability</span></li>
<li><span style="font-size: medium;">&middot;</span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <span style="font-family: Calibri; font-size: medium;">Eco-friendliness</span></li>
<li><span style="font-size: medium;">&middot;</span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <span style="font-family: Calibri; font-size: medium;">Increased substituent tolerance</span></li>
<li><span style="font-size: medium;">&middot;</span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <span style="font-family: Calibri; font-size: medium;">Relative safety</span></li>
</ul>
</div>
<p style="text-align: justify;"><em><br clear="all" /> </em></p>
<p style="text-align: justify;"><span style="font-family: Calibri;"><em><span style="font-size: medium;">p</span></em><span style="font-size: medium;">-Halogenation also offers some of these advantages, in particular regiospecificity, efficiency and safety. The advantages of our approach here is in what we leave out, not what materials we put in. When utilized in tandem, these three protocols present a formidable array of accesses to, in particular, all of the three tri-substituted and all of the three tetra-substituted arrangements of benzene substitution. Each of these unique arrangements exhibit transformable substituents. In other words, each can function as a regiospecific aromatic building block for medicinals, pharmaceuticals, even materials that would demand a particular pattern of aromatic substitution. Above is an example of a 1,2,4,5- tetra-substituted pharmaceutical, ciprofloxacin, which could potentially be regiospecifically synthesized using chemistry developed in our program.</span></span></p>
    [Section_Field2] => PUBLICATIONS
    [Section_Value2] => <p>U.S. Patent 3,111,541, Novel Aromatic Sulfides and Method of Preparing Same.<br />&nbsp;<br />Introduction of Substituents at Position 2 of Dimethylaminomethylferrocene through Lithiation. D. W. Slocum, B. W. Rockett and C. R. Hauser, Chemistry and Industry, 1831 (1964).<br />&nbsp;<br />Ring Metalation of Dimethylaminomethylferrocene with Butyllithium and Condensations with Electrophilic Compounds. Synthesis of 1,2-Disubstituted Ferrocenes.&nbsp; D. W. Slocum, B. W. Rockett and C. R. Hauser, Journal of the American Chemical Society, <span style="text-decoration: underline;">87</span>, 1241 (1965).<br />&nbsp;<br />The Absolute Configuration of 2,2'-Dichloro-6-6'-dimethylbiphenyl-4,4'-diamine.&nbsp; D. W. Slocum and K. Mislow, Journal of Organic Chemistry, <span style="text-decoration: underline;">30</span>, 2152 (1965).<br />&nbsp;<br />Magnetic Nonequivalence of Methylene Group Protons in 1,2-Disubstituted Ferrocenes.&nbsp; P. Smith, J. J. McLeskey, III, and D. W. Slocum, Journal of Organic Chemistry, <span style="text-decoration: underline;">30</span>, 4356 (1965).<br />&nbsp;<br />Mass Spectral Fragmentation Patterns of Certain Isomeric Ferrocenes. D. W. Slocum, R. Lewis and G. J. Mains, Chemistry and Industry, 2095 (1966).<br />&nbsp;<br />Reactions of Certain Ferrocene Compounds Leading to a Ferrocenyl Ethyl Ether. D. W. Slocum, B. Silverman, B. W. Rockett and C. R. Hauser, Journal of Organic Chemistry, <span style="text-decoration: underline;">32</span>, 464 (1967).<br />&nbsp;<br />Electronic Effects in the Ferrocene Ring System by Proton Magnetic Resonance Spectroscopy.&nbsp; D. W. Slocum, T. R. Engelmann, R. Lewis and R. J. Kurland, Journal of Chemical and Engineering Data, <span style="text-decoration: underline;">13</span>, 378 (1968).<br />&nbsp;<br />Comparative Behavior Upon Lithiation of Dimethylaminomethylferrocene and &#61476;-Phenethyldimethylamine.&nbsp; D. W. Slocum, T. R. Engelmann and C. A. Jennings, Australian Journal of Chemistry, <span style="text-decoration: underline;">21</span>, 2319 (1968).<br />&nbsp;<br />Reduction of Ferrocene Methiodides with Sodium in Liquid Ammonia; a Route to Alkyl Ferrocenes.&nbsp; D. W. Slocum and W. Jones, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">15</span>, 262 (1968).<br />&nbsp;<br />Metalation of Metallocenes.&nbsp; D. W. Slocum, T. R. Engelmann, C. R. Ernst, C. A. Jennings, W. E. Jones, B. Koonsvitsky, J. Lewis and P. Shenkin, Journal of Chemical Education, <span style="text-decoration: underline;">46</span>, 144 (1969).<br />&nbsp;<br />Reduction of Ferrocene Methiodides; Synthesis of the Dimethylferrocenes.&nbsp; D. W. Slocum, W. Jones, T. Crimmens and C. R. Hauser, The Journal of Organic Chemistry, <span style="text-decoration: underline;">34</span>, 1973 (1969)<br />&nbsp;<br />Ortho Lithiation of N,N-Dimethylbenzenesulfonamide by n-Butyllithium.&nbsp; Condensation with Electrophilic Compounds.&nbsp; H. Watanabe, R. A. Schwartz, C. R. Hauser, J. Lewis and D. W. Slocum, Canadian Journal of Chemistry, <span style="text-decoration: underline;">47</span>, 1543 (1969).<br />&nbsp;<br />The Coordination Effect of Oxygen in the 2-Metalation of Ferrocenes.&nbsp; D. W. Slocum and B. P. Koonsvitsky, Chemical Communications, 846 (1969).<br />&nbsp;<br />An Analysis of Diastereotopic Protons in the 2-Halo Dimethylaminomethylferrocenes.&nbsp; D. W. Slocum and T. R. Engelmann, Journal of Organic Chemistry, <span style="text-decoration: underline;">34</span>, 4101 (1969).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocene Systems. II. Racemization of (+)-1,2(&#61474;-Ketotetramethylene)fer-rocene.&nbsp; D. W. Slocum, S. P. Tucker and T. R. Engelmann, Tetrahedron Letters, 621 (1970).<br />&nbsp;<br />Rate and Orientation Effect of TMEDA on Directed Lithiation Reactions.&nbsp; D. W. Slocum, G. Book and C. A. Jennings, Tetrahedron Letters, 3443 (1970).<br />&nbsp;<br />The Synthesis and Synthetic Utility of 2-Chloromercuridimethylaminomethylferrocene.&nbsp; D. W. Slocum and T. R. Engelmann, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">24</span>, 753 (1970).<br />&nbsp;<br />2-Metalation of Dimethylaminoethylferrocene with Butyllithium and Condensations with Electrophilic Reagents.&nbsp; Synthesis of 2-Substituted Vinyl Ferrocenes.&nbsp; D. W. Slocum, C. A. Jennings, T. R. Engelmann, B. W. Rockett and C. R. Hauser, Journal of Organic Chemistry, <span style="text-decoration: underline;">36</span>, 377 (1971).<br />&nbsp;<br />Directed Metalation of Certain Thiophene Compounds.&nbsp; D. W. Slocum and P. L. Gierer, Chemical Communications, 305 (1971).<br />&nbsp;<br />A One-Step Preparation of 1,2-(&#61474;-Ketotetramethylene)ferrocene.&nbsp; D. W. Slocum, S. Tucker, J. Davis and T. R. Engelmann, Synthesis in Inorganic and Metalorganic Chemistry, <span style="text-decoration: underline;">1</span>, 93 (1971).<br />&nbsp;<br />Metallocene Homoannular Electronic Effects.&nbsp; D. W. Slocum and C. R. Ernst, Organometallic Chemistry Reviews, Section A, <span style="text-decoration: underline;">6</span>, 337 (1970).<br />&nbsp;<br />The Two Faces of D and L Nomenclature.&nbsp; D. W. Slocum, D. Sugarman and S. P. Tucker, Journal of Chemical Education, <span style="text-decoration: underline;">48</span>, 597 (1971).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocene Systems. III.&nbsp; Stereochemistry of the Diastereomeric 2,2'-Bis(dimethylaminomethyl)biferrocenyls.&nbsp; D. W. Slocum and D. I. Sugarman, Tetrahedron Letters, 3287 (1971).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocene Systems. IV.&nbsp; Some Aspects of the Contribution of Conformer Population to the Magnetic Nonequivalence of Diastereotopic Nuclei.&nbsp; D. W. Slocum and F. Stonemark, Tetrahedron Letters, 3291 (1971).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocenes, I. Electronic Effects of Electron Donating Groups on the Ferrocene System.&nbsp; D. W. Slocum, P. S. Shenkin, T. R. Engelmann and C. R. Ernst, Tetrahedron Letters, 4429 (1971).<br />&nbsp;<br />Shielding Effects of the Diphenylcarbinol Substituent in Certain Anisole Derivatives: A Method for the Determination of the Site of Metalation.&nbsp; D. W. Slocum and C. A. Jennings, Chemical Communications, 54 (1972).<br />&nbsp;<br />Directed Metalation Reactions. II.&nbsp; Demonstration of Directed Lithiation at the 2-Position of Methoxy- and Chloroferrocene.&nbsp; D. W. Slocum, B. P. Koonsvitsky and C. R. Ernst, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">38</span>, 125 (1972).<br />&nbsp;<br />The Concentration Dependence of Hydroxyl Proton Multiplicity in the NMR Spectra of the &#61476;-Chloroethanols.&nbsp; D. W. Slocum and C. A. Jennings, Tetrahedron Letters, 3543 (1972).<br />&nbsp;<br />Determination of Intramolecular Hydrogen Bonding in 2-Haloethanols by Methylene Proton Coupling Constant Variations.&nbsp; C. A. Jennings and D. W. Slocum, Tetrahedron Letters, 3547 (1972).<br />&nbsp;<br />Cyclopentadienyl Complexes of Chromium, Molybdenum and Tungsten.&nbsp; K. W. Barnett and D. W. Slocum, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">44</span>, 1 (1972).<br />&nbsp;<br />The Organic Chemistry of Transition Metal Ligands. I.&nbsp; Duroquinone.&nbsp; D. W. Slocum and T. R. Engelmann, Journal of The American Chemical Society, <span style="text-decoration: underline;">94</span>, 8596 (1972).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocene Systems. VI.&nbsp; Electronic Effects in the Alkylferrocenes.&nbsp; D. W. Slocum, W. E. Jones and C. R. Ernst, Journal of Organic Chemistry, <span style="text-decoration: underline;">37</span>, 4278 (1972).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocene Systems. V.&nbsp; Orientation in Electrophilic Substitution of Methoxyferrocene.&nbsp; D. W. Slocum and C. R. Ernst, Tetrahedron Letters, 5217 (1972).<br />&nbsp;<br />Fundamental Studies of Substituted Ferrocenes. VII.&nbsp; PMR Resonance Effects in Trimethylsilylferrocene.&nbsp; D. W. Slocum and C. R. Ernst, Journal of Organic Chemistry, <span style="text-decoration: underline;">38</span>, 1620 (1973).<br />&nbsp;<br />Directed Metalation Reactions. III.&nbsp; Contribution of Oxygen Coordination in the Lithiation of o-t-Butylanisole.&nbsp; D. W. Slocum and B. P. Koonsvitsky, Journal of Organic Chemistry, <span style="text-decoration: underline;">38</span>, 1675 (1973).<br />&nbsp;<br />Directed Metalation Reactions. IV.&nbsp; 2-Metalation of N-Substituted Ferrocene-carboxamides.&nbsp; D. W. Slocum and F. E. Stonemark, Journal of Organic Chemistry, <span style="text-decoration: underline;">38</span>, 1677 (1973).<br />&nbsp;<br />Directed Metalation Reactions. V.&nbsp; Metalation and Rearrangement in Substituted 2-Thiophenesulfonamides.&nbsp; D. W. Slocum and P. L. Gierer, Journal of Organic Chemistry, <span style="text-decoration: underline;">38</span>, 4189 (1973).<br />&nbsp;<br />Reduction of Ferrocenylmethyl Quaternary Ammonium Iodides: Synthesis of Methylferrocenes.&nbsp; D. W. Slocum, R. L. Marchal and W. E. Jones.&nbsp; Journal of Organometallic Chemistry, <span style="text-decoration: underline;">72</span>, 227 (1974).<br />&nbsp;<br />Directed Metalation Reactions.&nbsp; A Specific Route to 1,2,3-Trisubstituted and 1,3-Disubstituted Ferrocenes.&nbsp; D. W. Slocum, R. L. Marchal and W. E. Jones, Chemical Communications, 967 (1974).<br />&nbsp;<br />Directed Metalation of Model Adrenaline Compounds.&nbsp; D. W. Slocum and W. Achermann, Chemical Communications, 968 (1974).<br />&nbsp;<br />Directed Metalation Reactions. VI. Competition of Substituents for Ortho Direction of Metalation in Substituted Anisoles.&nbsp; D. W. Slocum and C. A. Jennings, Journal of Organic Chemistry, <span style="text-decoration: underline;">41</span>, 3653 (1976).<br />&nbsp;<br /><br /></p>
    [Section_Field3] => 
    [Section_Value3] => <p>Directed Metalation Reactions. VII.&nbsp; Directed Metalation of Methoxymethyl-ferrocene; 2- and 1'-Metalated Ferrocene Intermediates.&nbsp; D. W. Slocum and B. P. Koonsvitsky, Journal of Organic Chemistry, <span style="text-decoration: underline;">41</span>, 3664 (1976).<br />&nbsp;<br />Directed Metalation Reactions. VIII.&nbsp; Directed Metalation of 3-Mono- and 2,5-Disubstituted Thiophenes.&nbsp; D. W. Slocum and P. L. Gierer, Journal of Organic Chemistry, <span style="text-decoration: underline;">41</span>, 4668 (1976).<br />&nbsp;<br />Tetraphenylborate Zwitterionic Transition Metal Complexes: Stable Homogeneous Catalysts.&nbsp; D. A. Owen, A. Siegel, R. Lin, D. W. Slocum, B. Conway, M. Moronski and S. Duraj, Annals of the New York Academy of Sciences, <span style="text-decoration: underline;">333</span>, 90 (1980).<strong>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; </strong><br />&nbsp;<br />Synthesis of Ring Substituted Potassium Tetraphenylborate Salts.&nbsp; D. W. Slocum, S. Duraj and K. Webber, Synthesis and Reactivity in Inorganic and Metal-organic Chemistry, <span style="text-decoration: underline;">10</span>, 261 (1980).<br />&nbsp;<br />A Unique Deuterium Exchange Reaction in Certain Substituted Ferrocenes.&nbsp; D. W. Slocum, D. L. Beach, C. R. Ernst, R. Fellows, M. Moronski, B. Conway and J. Bencini, Chemical Communications, 1043 (1980).<br />&nbsp;<br />The Potential of &#61506;-Bonded Organometallic Polymers in Catalyst Design.&nbsp; D. W. Slocum, B. Conway, M. Hodgman, K. Kuchel, M. Moronski, R. Noble, K. Webber and S. Duraj, Journal of Macromolecular Science-Chemistry, <span style="text-decoration: underline;">16</span>, 357 (1981).<br />&nbsp;<br />Organometallic Chemistry in the People's Republic of China,&nbsp; D. W. Slocum and<br />M. D. Rausch, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, <span style="text-decoration: underline;">11</span>, 509 (1981).<br />&nbsp;<br />The Preparation of Several N-Substituted and N,N-Disubstituted Ferrocenesulfonamides.&nbsp; D. W. Slocum and W. Achermann, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, <span style="text-decoration: underline;">12</span>, 397 (1982).<br />&nbsp;<br />Equilibria Involving Synthesis Gas and Transition Metal Derivatives.&nbsp; D. W. Slocum, Annals of the New York Academy of Sciences, <span style="text-decoration: underline;">415</span>, 314 (1983).<br />&nbsp;<br />Models for Highly Phenylated Transition Metal-containing Polymers; Derivatives of the Pentaphenylcyclopentadienyl Ligand.&nbsp; D. W. Slocum, S. Johnson, M. Matusz, S. Duraj, J. L. Cmarik, K. M. Simpson and D. A. Owen.&nbsp; Polymeric Materials Science and Engineering, <span style="text-decoration: underline;">49</span>, 353 (1983).<br />&nbsp;<br />Reductive Substitution of Cobaltocene; Displacements of a Cyclopentadienyl Group on Cobaltocene and Replacement of Same by a Diene Moiety.&nbsp; D. W. Slocum, T. R. Engelmann, R. Fellows, M. Moronski and S. Duraj, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">260</span>, C21 (1984).<br />&nbsp;<br />Reductive Substitution of Nickelocene; Interception of a Monohydrido Intermediate in the Hydrogenation of 2,3,4,5-Tetraphenylcyclopentadienone (tetracyclone).&nbsp; D. W. Slocum, M. Moronski, R. Gooding and S. Duraj, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">260</span>, C26 (1984).<br />&nbsp;<br />Substituent Effects on Alkylferrocenes in Molten Salt Mixtures. D. W. Slocum, A. L. Edgecombe, S. Fowler, H. F. Gibbard and J. Phillips, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">363</span>, 141 (1989).<br />&nbsp;<br />Substituent Effects on Ferrocenes in Aluminum Chloride/Butyl Pyridinium Chloride Molten Salt Mixtures.&nbsp; D. W. Slocum, A. L. Edgecombe, J. W. Fowler, H. F. Gibbard and J. Phillips, Organometallics, <span style="text-decoration: underline;">9</span>, 307 (1990).<br />&nbsp;<br />Pentaphenylcyclopentadienyl Carbonyl Complexes of Groups VI and VIII Transition Metals.&nbsp; D. W. Slocum, S. A. Duraj, A. Clearfield, R. Peascoe and M. Matusz, Journal of Macromolecular Science, Chemistry, <span style="text-decoration: underline;">A27</span> (9-11), 1405 (1990).<br />&nbsp;<br />New Approaches to the Preparation of Soluble Phthalocyanine Complexes.&nbsp; M. J. Chen, J. W. Rathke, S. Sinclair and D. W. Slocum.&nbsp; Journal of Macromolecular Science, Chemistry (invited contribution), <span style="text-decoration: underline;">A27</span> (9-11), 1415 (1990).<br />&nbsp;<br />A Predicative Model for Certain Directed Metalations, I; Applications to the Behavior of Anisole.&nbsp; D. W. Slocum, R. Moon, J. Thompson, D. S. Coffey, J. D. Li, M. G. Slocum, R. Gayton-Garcia and A. Siegel, Tetrahedron Letters, <span style="text-decoration: underline;">35</span>, 385 (1994).<br />&nbsp;<br />A Predicative Model for Certain Directed Metalations, II; Applications to the Behavior of p-Fluoroanisole.&nbsp; D. W. Slocum, D. S. Coffey, A. Siegel and P. Grimes, Tetrahedron Letters, <span style="text-decoration: underline;">35</span>, 389 (1994).<br />&nbsp;<br />A Predicative Model for Certain Directed Metalations, III; Methyl Group Influence and Interference in the Directed Metalation of p-Methylanisole (p-MA).&nbsp; D. W. Slocum, J. Thompson and C. Friesen, Tetrahedron Letters, <span style="text-decoration: underline;">36</span>, 8171 (1995).<br />&nbsp;<br />A Predicative Model for Certain Directed Metalations, IV; the Dynamic Behavior of the Organolithio Intermediates formed upon Metalation of p-Dimethoxybenzene (p-DMB).&nbsp; D. W. Slocum, G. Hayes and N. Kline, Tetrahedron Letters, <span style="text-decoration: underline;">36</span>, 8175 (1995).<br />&nbsp;<br />Media Effects in Directed Metalation. D. W. Slocum, D. Reed, F. Jackson, III and C. Friesen, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">512</span>, 265 (1996).<br />&nbsp;<br />Ortho-Metalation of p-Chloroanisole: A Media Study. D. W. Slocum and P. Dietzel, Tetrahedron Letters, <span style="text-decoration: underline;">40</span>, 1823 (1999).<br />&nbsp;<br />Substrate-promoted ortho-Metalation in Hydrocarbon Solvents. D. W. Slocum, J. Ray and P. Shelton, Tetrahedron&nbsp; Letters, <span style="text-decoration: underline;">43</span>, 6071 (2002).<br />&nbsp;<br />Metalation in Hydrocarbon Solvents:&nbsp; The Mechanistic Aspects of Substrate-Promoted ortho-&nbsp;&nbsp; Metalations.&nbsp; D. W. Slocum, C. Harrison, G. Jackson, R. LaMastus, J. Ray, P. Shelton, A. Walstrom, J. M. Wilcox and R. W. Holman, Tetrahedron&nbsp; <span style="text-decoration: underline;">59</span>, 8275 (2003).<br />&nbsp;<br />Metalations in Hydrocarbon Solvents; Media Effects on n-BuLi Reactivity. D. W. Slocum,&nbsp; &nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; &nbsp;A.&nbsp;Carroll, P. Dietzel, S. Eilerman, J. P. Culver, B. McClure, S. Brown and R. W. Holman, Tetrahedron&nbsp; Letters, <span style="text-decoration: underline;">47</span>, 865 (2006).<br />&nbsp;<br />Metalations Utilizing Aryllithiums; <em>ortho</em>-Functionalization of&nbsp;&nbsp; <em>p</em>-Bromoanisole (<em>p</em>-BrA<strong>).&nbsp;&nbsp;</strong>D.W. Slocum, T. L. Reece, R. D. Sandlin, T. K. Reinscheld and P. E. Whitley, Tetrahedron Letters, <span style="text-decoration: underline;">50</span>, 1593 (2009).<br />&nbsp;<br />Metalation of o-Methylanisole (o-MA); an Optional-Site Selectivity Reassessment. D. W. Slocum, Sophia Wang, Christopher B. White and Paul E. Whitley, Tetrahedron, <span style="text-decoration: underline;">66</span>, 4939-4942 (2010).<br />&nbsp;<br />Halogen/Lithium Exchange in Hydrocarbon Media; Basic and Continuous Reactor Studies. D. W. Slocum, Damir Kusmic, Jeffrey C. Raber, Thomas K. Reinscheld and Paul E. Whitley, Tetrahedron Letters, <span style="text-decoration: underline;">51</span>, 4793-4796 (2010).<br /><em>&nbsp;</em><br /><em>&nbsp;p</em>-Iodinations in Hydrocarbon Media. Slocum, D. W.; Telkin, Kristen C.; Nguyen, Quang; Whitley, Paul E.;&nbsp;Fouzia, Begum. Tetrahedron Letters., <span style="text-decoration: underline;">52</span>, 7141-7145 (2011).<br />&nbsp;<br />Near Ambient Temperature Halogen/Lithium Exchange of p-Bromoanisole and Related Substrates; Flow/Batch Studies. D. W. Slocum, Thomas K. Reinscheld, Nick D. Austin, &nbsp;Damir&nbsp;Kusmic and Paul E. Whitley, Synthesis (invited paper), 2531-2536 (2012).<br />&nbsp;<br />Ortho-Lithiations Reassessed: the Advantages of Deficiency Catalysis in Hydrocarbon Media. D. W. Slocum, Thomas K. Reinscheld, Christopher B. White, Michael D. Timmons,&nbsp;&nbsp;Phillip A.&nbsp;Shelton, Matthew G. Slocum, Rebecca D. Sandlin, Erica G. Holland, &nbsp;Damir &nbsp;Kusmic, John A.&nbsp;Jennings, Kristen C. Tekin, Quang Nguyen, Steven J. Bush, Julia M.&nbsp;&nbsp;&nbsp;Keller and Paul E.&nbsp;Whitley, Organometallics, <span style="text-decoration: underline;">32</span>, 1674-1686 (2013).</p>
    [Section_Field4] => REVIEW ARTICLES/ BOOK CHAPTERS
    [Section_Value4] => <p>Electronic Effects in Metallocenes and Certain Related Systems, D. W. Slocum and C. R. Ernst, in "Advances in Organometallic Chemistry," Vol. 10, Academic Press, New York, NY, 1972, pp. 79-114.<br />&nbsp;<br />Carbanions, D. W. Slocum and E. Kaiser, in "Organic Reactive Intermediates," Academic Press, New York, NY, 1973, pp. 337-422.<br />&nbsp;<br />Directed Metalation, D. W. Slocum, and D. Sugarman, in Advances in Chemistry Series, Number 130, "Polyaminechelated Alkali Metal Compounds," A. Langer, editor, American Chemical Society, Washington, D.C., 1974, pp. 222-247.<br />&nbsp;<br />Lithium, Annual Survey covering the year 1973, Journal of Organometallic Chemistry, <span style="text-decoration: underline;">95</span>, 1 (1975).<br />&nbsp;<br />Activation of Duroquinone and Potentially Other Dienes <span style="text-decoration: underline;">via</span> Transition Metal Complexation, D. W. Slocum, T. R. Engelmann, and (in part) R. Fellows, L. Jennings and M. Moronski in "Catalysis in Organic Syntheses, 1977," G. V. Smith, ed., Academic Press, New York, NY, 1977, pp. 175-188.<br />&nbsp;<br />&nbsp;<br />Real and Proposed Organometallic &#61506;-Monomers, D. W. Slocum, M. D. Rausch, and A. Siegel, in "Organometallic Polymers," C. U. Pittman, C. E. Carraher and J. Sheats, eds., Academic Press, New York, NY, 1978, pp. 39-51.<br />&nbsp;<br />Chemicals from Coal: the Cobalt Octacarbonyl Catalyzed Homologation of Methanol to Ethanol, D. W. Slocum, in "Catalysis in Organic Synthesis, 1978," W. Jones, ed., Academic Press, New York, NY, 1980, pp. 245-176.<br />&nbsp;<br />The Role of &#61488;<sup>5</sup> &#61494; &#61488;<sup>1</sup> (&#61506; &#61494; &#61510;)&nbsp; Rearranging Cyclopentadienyls in Homogeneous Catalyst Design.&nbsp; D. W. Slocum, S. Duraj, J. Bencini, K. Webber, R. Noble, K. Kuchel, M. Hodgman, D. A. Owen, A. Siegel and J. Rathke, in "Fundamental Research in Organometallic Chemistry," M. Tsutsui, Y. Ishii, and Y. Z. Yaozeng, editors, Van Nostrand Reinhold Company, New York, NY, and Science Press, Beijing, PRC, 1982, pp. 901-922.<br />&nbsp;<br />The Potential of &#61506;-Bonded Organometallic Polymers in Catalyst Design.&nbsp; D. W. Slocum, B. Conway, M. Hodgmen, K. Kuchel, M. Moronski, R. Noble, K. Webber, S. Duraj, A. Siegel and D. A. Owen, in "Organometallic Polymers: Perspectives," C. Carraher, Jr., and J. Sheats, ed., Marcel Dekker, New York, NY, 1982, pp. 357-368.<br />&nbsp;<br />Models for Highly Phenylated &#61506;-Bonded Transition Metal Containing Polymers; &nbsp;Chemistry of the &nbsp;Pentapheylcyclopentadienyl Ligand.&nbsp; D. W. Slocum, S. Johnson, M. Matusz, S. Duraj, J. L. Cmarik, K. M. Simpson, T. H. Pritchett and D. A. Owen in "Inorganic and Organometallic Polymers," C. Carraher, C. U. Pittman and J. Sheats, eds., Plenum Press, New York, NY, 1985, pp. 59-68.<br />&nbsp;<br />Sections "Metallocenes" and "Organometallic Compound," in Encyclopedia of Science and Technology, McGraw-Hill Book Company, New York, NY, 1987, pp. 53-55 and 519-523, respectively.<br />&nbsp;<br />Sections "Metallocenes" and "Organometallic Compound" in Encyclopedia of Science and Technology, McGraw-Hill Book Company, New York, NY, 1992, pp 50-53 and pp 536-540, respectively.<br />&nbsp;<br />&ldquo;Metal-halogen Exchange (M &#61688; X) of Aryl and Heteroaryl Ring Systems Using Alkyllithiums,&rdquo; D. W. Slocum, Lithium Link Newsletter, FMC Lithium Division, Gastonia, NC, Winter, 1993.<strong>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; </strong><br />&nbsp;<br />Section "ortho-Lithioanisole" in Encyclopedia of Reagents for Organic Synthesis, L.A. Paquette, Ed., John Wiley &amp;&nbsp; &nbsp;Sons, New York, NY, 1995, pp 2970-2973.<br />&nbsp;<br />Section &ldquo;Metallocenes&rdquo; in Encyclopedia of Science and Technology, 8th Edition, Volume 11, McGraw-Hill Book &nbsp;&nbsp;Company, New York, NY, 1997, pp. 61-64.<br />&nbsp;<br />&ldquo;Halogenation of Intermediate Lithioarenes and Lithiohetarenes,&rdquo; D. W. Slocum and P. Shelton, Lithium Link &nbsp;&nbsp;Newsletter, FMC Lithium Division, Gastonia, NC, Fall, 2005.<br />&nbsp;<br />&nbsp;&ldquo;Processing Aryllithium and Hetaryllithium Intermediates: Formation of Halogen and Chalcogen Derivatives,&rdquo;&nbsp;&nbsp;&nbsp; D. W. Slocum, P. Shelton and K. Moran, Synthesis (invited review) (20) 3477-3498 (2005).<br />&nbsp;<br />&ldquo;Aryllithiums and Heteryllithiums; Generation and Reactivity&rdquo; in The Lightest Metals: Science and Technology&nbsp;from Lithium to Calcium, John Wiley and Sons, New York, NY (invited chapter)&nbsp;(22 printed pages - in press), D. W. Slocum.</p>
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Chemistry - Emeritus Faculty


Dr. David Hartman

Dr. David Hartman
- Emeritus Professor

Dr. Norman Hunter

Dr. Norman Hunter
- Professor Emeritus

Dr. Wei-Ping Pan

Dr. Wei-Ping Pan
- Assistant to the President & Sumpter Emeritus Professor of Chemistry

Dr. Lowell Shank

Dr. Lowell Shank
- Emeritus Professor, Director, Kentucky Science Olympiad

Dr. Donald Slocum

Dr. Donald Slocum
- Emeritus Research Professor

Dr. Curtis Wilkins

Dr. Curtis Wilkins
- Emeritus Professor


 

 


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